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Crystal structure of tris-(N-methyl-salicylaldiminato-?(2) N,O)vanadium(III).

ABSTRACT: The structure of the title complex, [V(C8H8NO)3], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl-alicylaldiminate ligands within a slightly distorted mer-N3O3 octa-hedral geometry. In the crystal structure, the mol-ecules are linked via C-H?O hydrogen bonds into supra-molecular chains that extend along the c axis.

SUBMITTER: Hilbert J 

PROVIDER: S-EPMC4719845 | biostudies-other | 2015 Dec

REPOSITORIES: biostudies-other

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Crystal structure of tris-(N-methyl-salicylaldiminato-κ(2) N,O)vanadium(III).

Hilbert Jessica J   Kabus Sven S   Näther Christian C   Bensch Wolfgang W  

Acta crystallographica. Section E, Crystallographic communications 20151118 Pt 12

The structure of the title complex, [V(C8H8NO)3], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl-alicylaldiminate ligands within a slightly distorted mer-N3O3 octa-hedral geometry. In the crystal structure, the mol-ecules are linked via C-H⋯O hydrogen bonds into supra-molecular chains that extend along the c axis. ...[more]