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Crystal structure of TiBi2.

ABSTRACT: Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693?K. The title compound is isostructural with CuMg2 (ortho-rhom-bic Fddd symmetry). Ti atoms are located in square anti-prisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane inter-lace one another.

SUBMITTER: Watanabe K 

PROVIDER: S-EPMC5120700 | biostudies-other | 2016 Sep

REPOSITORIES: biostudies-other

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Crystal structure of TiBi<sub>2</sub>.

Watanabe Kei K   Yamane Hisanori H  

Acta crystallographica. Section E, Crystallographic communications 20160805 Pt 9

Black granular single crystals of monotitanium dibismuth, TiBi<sub>2</sub>, were synthesized by slow cooling of a mixture of Bi and Ti from 693 K. The title compound is isostructural with CuMg<sub>2</sub> (ortho-rhom-bic <i>Fddd</i> symmetry). Ti atoms are located in square anti-prisms of Bi atoms. The network of one type of Bi atom spirals along the <i>a</i>-axis direction while honeycomb layers of the other type of Bi atom spreading in the <i>ab</i> plane inter-lace one another. ...[more]