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Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol-yne reaction.

ABSTRACT: Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.

SUBMITTER: Lang M 

PROVIDER: S-EPMC5238528 | biostudies-other | 2016

REPOSITORIES: biostudies-other

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Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol-yne reaction.

Lang Mathias M   Schade Alexandra A   Bräse Stefan S  

Beilstein journal of organic chemistry 20161129

Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and <i>pseudo</i>-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents. ...[more]

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