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Simultaneously Toughening and Strengthening Soy Protein Isolate-Based Composites via Carboxymethylated Chitosan and Halloysite Nanotube Hybridization.

ABSTRACT: Chemical cross-linking modification can significantly enhance the tensile strength (TS) of soy protein isolate (SPI)-based composites, but usually at the cost of a reduction in the elongation at break (EB). In this study, eco-friendly and high-potential hybrid SPI-based nanocomposites with improved TS were fabricated without compromising the reduction of EB. The hybrid of carboxymethylated chitosan (CMCS) and halloysite nanotubes (HNTs) as the enhancement center was added to the SPI and 1,2,3-propanetriol-diglycidyl-ether (PTGE) solution. The chemical structure, crystallinity, micromorphology, and opacity properties of the obtained SPI/PTGE/HNTs/CMCS film was analyzed by the attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and UV-Vis spectroscopy. The results indicated that HNTs were uniformly dispersed in the SPI matrix without crystal structure damages. Compared to the SPI/PTGE film, the TS and EB of the SPI/PTGE/HNTs/CMCS film were increased by 57.14% and 27.34%, reaching 8.47 MPa and 132.12%, respectively. The synergy of HNTs and CMCS via electrostatic interactions also improved the water resistance of the SPI/PTGE/HNTs/CMCS film. These films may have considerable potential in the field of sustainable and environmentally friendly packaging.

SUBMITTER: Liu X

PROVIDER: S-EPMC5554034 | biostudies-other | 2017 Jun

REPOSITORIES: biostudies-other

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Project description:As the fundamental structural protein in mammals, collagen transmits cyclic forces that are necessary for the mechanical function of tissues, such as bone and tendon. Although the tissue-level mechanical behavior of collagenous tissues is well understood, the response of collagen at the nanometer length scales to cyclical loading remains elusive. To address this major gap, we cyclically stretched individual reconstituted collagen fibrils, with average diameter of 145?±?42?nm, to small and large strains in the partially hydrated conditions of 60% relative humidity. It is shown that cyclical loading results in large steady-state hysteresis that is reached immediately after the first loading cycle, followed thereafter by limited accumulation of inelastic strain and constant initial elastic modulus. Cyclic loading above 20% strain resulted in 70% increase in tensile strength, from 638?±?98?MPa to 1091?±?110?MPa, and 70% increase in toughness, while maintaining the ultimate tensile strain of collagen fibrils not subjected to cyclic loading. Throughout cyclic stretching, the fibrils maintained a steady-state hysteresis, yielding loss coefficients that are 5-10 times larger than those of known homogeneous materials in their modulus range, thus establishing damping of nanoscale collagen fibrils as a major component of damping in tissues. STATEMENT OF SIGNIFICANCE: It is shown that steady-state energy dissipation occurs in individual collagen fibrils that are the building blocks of hard and soft tissues. To date, it has been assumed that energy dissipation in tissues takes place mainly at the higher length scales of the tissue hierarchy due to interactions between collagen fibrils and fibers, and in limited extent inside collagen fibrils. It is shown that individual collagen fibrils need only a single loading cycle to assume a highly dissipative, steady-state, cyclic mechanical response. Mechanical cycling at large strains leads to 70% increase in mechanical strength and values exceeding those of engineering steels. The same cyclic loading conditions also lead to 70% increase in toughness and loss properties that are 5-10 times higher than those of engineering materials with comparable stiffness.

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Simultaneously Toughening and Strengthening Soy Protein Isolate-Based Composites via Carboxymethylated Chitosan and Halloysite Nanotube Hybridization.

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