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Synthesis of the Sex Pheromone of the Tea Tussock Moth Based on a Resource Chemistry Strategy.


ABSTRACT: Synthesis of the sex pheromone of the tea tussock moth in 33% overall yield over 10 steps was achieved. Moreover, the chiral pool concept was applied in the asymmetric synthesis. The synthesis used a chemical available on a large-scale from recycling of wastewater from the steroid industry. The carbon skeleton was constructed using the C4+C5+C8 strategy. Based on this strategy, the original chiral center was totally retained.

SUBMITTER: Zhang HL 

PROVIDER: S-EPMC6100017 | biostudies-other | 2018 Jun

REPOSITORIES: biostudies-other

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Synthesis of the Sex Pheromone of the Tea Tussock Moth Based on a Resource Chemistry Strategy.

Zhang Hong-Li HL   Sun Zhi-Feng ZF   Zhou Lu-Nan LN   Liu Lu L   Zhang Tao T   Du Zhen-Ting ZT  

Molecules (Basel, Switzerland) 20180604 6


Synthesis of the sex pheromone of the tea tussock moth in 33% overall yield over 10 steps was achieved. Moreover, the chiral pool concept was applied in the asymmetric synthesis. The synthesis used a chemical available on a large-scale from recycling of wastewater from the steroid industry. The carbon skeleton was constructed using the C4+C5+C8 strategy. Based on this strategy, the original chiral center was totally retained. ...[more]

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