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Toward the Total Synthesis of Scleritodermin A: Preparation of the C(1)-N(15) Fragment.


ABSTRACT: The synthesis of the C(1)-N(15) fragment of the marine natural product Scleritodermin A has been accomplished through a short and stereocontrolled sequence. Highlights of this route include the synthesis of the novel ACT fragment and the formation of the alpha-keto amide linkage by the use of a highly activated alpha, beta-ketonitrile.

PROVIDER: S-EPMC1832122 | BioStudies |

REPOSITORIES: biostudies

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