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Incorporation of hexafluorobutyne into furans or phenols via reaction with iron(0) carbene or vinylketene complexes.


ABSTRACT: Reaction of iron(0) carbene complexes with hexafluorobut-2-yne produces 3,4-bis(trifluoromethylated)furans in a process that is favored for electron rich carbenes. No traces of furannulation or benzannulation are observed with Group 6 Fischer carbenes. Reaction of hexafluorobut-2-yne with a vinylketene iron(0) complex gives a 2,3-bis-trifluoromethylated phenol.

SUBMITTER: Akhani RK 

PROVIDER: S-EPMC2629604 | BioStudies | 2009-01-01

REPOSITORIES: biostudies

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