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Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation.


ABSTRACT: This paper describes a catalytic asymmetric diamination process for terminal olefins at allylic and homoallylic carbons via formal C-H activation using di-tert-butyldiaziridinone as nitrogen source with a catalyst generated from Pd2(dba)3 and chiral phosphorus amidite ligand. A wide variety of readily available terminal olefins can be effectively diaminated in good yields with high regio-, diastereo-, and enantioselectivities.

SUBMITTER: Du H 

PROVIDER: S-EPMC2776772 | BioStudies | 2008-01-01

REPOSITORIES: biostudies

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