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Approaches to N-methylwelwitindolinone C isothiocyanate: facile synthesis of the tetracyclic core.


ABSTRACT: The synthesis of a functionalized, tetracyclic core of N-methylwelwitindolinone C isothiocyanate is reported. The approach features a convergent coupling between an indole iminium ion and a highly functionalized vinylogous silyl ketene acetal followed by an intramolecular palladium-catalyzed cyclization that proceeds via an enolate arylation.

SUBMITTER: Heidebrecht RW 

PROVIDER: S-EPMC2878383 | BioStudies | 2010-01-01T00:00:00Z

REPOSITORIES: biostudies

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