Conjugate addition of lithiated methyl pyridines to enones.
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ABSTRACT: Preparatively useful conjugate addition of lithiated methyl pyridines to cyclic and acyclic enones is reported. Addition of 2-picoline to 3-penten-2-one led to a concise synthesis of the alkaloids (+/-)-senepodine G and (+/-)-cermizine C.
SUBMITTER: Taber DF
PROVIDER: S-EPMC2921646 | BioStudies | 2010-01-01
REPOSITORIES: biostudies
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