Unknown

Dataset Information

0

1,1-Bis(4-fluoro-phen-yl)-3,4-dihydro-1H-1,3-oxazino[3,4-a]indole.


ABSTRACT: The title compound, C(23)H(17)F(2)NO, which crystallizes with two independent mol-ecules in the asymmetric unit, was prepared by the cyclization of 4-[2-bis-(4-fluoro-phen-yl)methyl-eneamino]but-3-yn-1-ol at room temperature. The mol-ecules display a tripod conformation. The two fluoro-phenyl rings make dihedral angles of 79.26?(2) and 85.87?(1)° [86.53?(1) and 83.67?(2)° in the second mol-ecule] with the indole ring, and the dihedral angles between the fluoro-phenyl rings are 67.74?(2) and 66.33?(2)°, respectively. Furthermore, the indole rings are located on the edge of the respective oxazine half-chair ring systems. Nonconventional C-H?? contacts between indole and fluoro-phenyl rings are observed.

SUBMITTER: Fu W 

PROVIDER: S-EPMC2959698 | BioStudies | 2008-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC3998398 | BioStudies
1000-01-01 | S-EPMC3569257 | BioStudies
1000-01-01 | S-EPMC3011398 | BioStudies
1000-01-01 | S-EPMC2977727 | BioStudies
1000-01-01 | S-EPMC3685127 | BioStudies
1000-01-01 | S-EPMC3998453 | BioStudies
1000-01-01 | S-EPMC3648276 | BioStudies
1000-01-01 | S-EPMC2969582 | BioStudies
1000-01-01 | S-EPMC2983722 | BioStudies
1000-01-01 | S-EPMC3051655 | BioStudies