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5-Iodo-2,7-dimethyl-3-phenyl-sulfinyl-1-benzofuran.


ABSTRACT: The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 5-iodo-2,7-dimethyl-3-phenyl-sulfanyl-1-benzofuran using 3-chloro-perbenzoic acid. The O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring is nearly perpendicular to the plane of the benzofuran fragment [89.15?(5)°]. The crystal structure is stabilized by an I?O halogen bond [I?O = 3.177?(2)?Å and C-I?O = 175.68?(6)°] linking mol-ecules into centrosymmetric dimers and by a weak C-H?? inter-action between a phenyl H atom and the furan ring of the benzofuran system.

SUBMITTER: Choi HD 

PROVIDER: S-EPMC2960312 | BioStudies | 2008-01-01T00:00:00Z

REPOSITORIES: biostudies

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