Unknown

Dataset Information

0

(Dicyanamido)[tris-(2-pyridylmeth-yl)amine]zinc(II) perchlorate.


ABSTRACT: In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal-bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak inter-molecular C-H?O and C-H?N hydrogen bonds. In addition, there are relatively close contacts between the O atoms of the perchlorate anion and symmetry-related pyridine rings [O?Cg = 3.179?(3) and 3.236?(3)?Å, where Cg is the centroid of a pyridine ring], and between the terminal N atom of the dicyanamide ligand and pyridine rings [N?Cg = 3.381?(4)-3.761?(3)?Å]. The central N atom of the dicyanamide ligand is disordered over two sites in an approximately 0.6:0.4 ratio.

SUBMITTER: Li H 

PROVIDER: S-EPMC2960752 | BioStudies | 2008-01-01

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC2961919 | BioStudies
1000-01-01 | S-EPMC2960646 | BioStudies
2010-01-01 | S-EPMC2983267 | BioStudies
2008-01-01 | S-EPMC2961423 | BioStudies
1000-01-01 | S-EPMC2977432 | BioStudies
1000-01-01 | S-EPMC3569189 | BioStudies
1000-01-01 | S-EPMC2971262 | BioStudies
2009-01-01 | S-EPMC2970226 | BioStudies
1000-01-01 | S-EPMC2971799 | BioStudies
2009-01-01 | S-EPMC2972168 | BioStudies