Browse
Submit Data
Databases
API
Help
Login

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

9-Oxo-4,5-diaza-fluoren-4-ium tetra-chloridoaurate(III)-4,5-diaza-fluoren-9-one (1/1).

ABSTRACT: The Au(III) atom in the title compound, (C(11)H(7)N(2)O)[AuCl(4)]·C(11)H(6)N(2)O, is in a nearly square-planar environment defined by four Cl atoms. The protonated 9-oxo-4,5-diaza-fluoren-4-ium cation forms an N-H?N hydrogen bond with the neutral 4,5-diaza-fluoren-9-one mol-ecule.

SUBMITTER: Safari N

PROVIDER: S-EPMC2968535 | BioStudies | 2009-01-01T00:00:00Z

REPOSITORIES: biostudies

ACCESS DATA

Json Xml

Similar Datasets

9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate.

Project description:The title compound, C(17)H(12)N(2)O·H(2)O, was synthesized by the reaction of 4,5-diaza-fluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH(4)Cl solution), and crystallizes with two organic mol-ecules and two water mol-ecules in the asymmetric unit. The 4,5-diaza-fluorene fragment is approximately planar, with r.m.s. deviations of 0.0448 and 0.0198?Å in the two mol-ecules. The dihedral angles between the 4,5-diaza-fluorene planes and the phenyl ring are 80.49?(6) and 76.57?(7)°. The crystal packing features O-H?N and O-H?O hydrogen bonds involving the bridging solvent water mol-ecules, which link the mol-ecules into a three-dimensional network.

2012-01-01 | S-EPMC3379391 | BioStudies

Tetra-aqua-(4,5-diaza-fluoren-9-one-?N,N')nickel(II) dinitrate.

Project description:The title compound, [Ni(C(11)H(6)N(2)O)(H(2)O)(4)](NO(3))(2), was prepared by the reaction of Ni(NO(3))(2) and 4,5-diaza-fluoren-9-one (dafo). The crystal packing consists of a three-dimensional network via O-H?O hydrogen bonds between the coordin-ated water mol-ecules and the nitrate anions. The Ni atom lies on a special position (Wyckoff position 4e, site symmetry 2), as does the carbonyl O atom.

2009-01-01 | S-EPMC2970992 | BioStudies

Hexaaqua-zinc(II) bis-(2,4,5-tricarboxybenzoate) 4,5-diaza-fluoren-9-one disolvate dihydrate.

Project description:The asymmetric unit of the title complex, [Zn(H(2)O)(6)](C(10)H(5)O(8))(2)·2C(11)H(6)N(2)O·2H(2)O, contains one half of the complex cation with the Zn(II) ion located on an inversion center, a monovalent 2,4,5-tricarboxybenzoate (1,2,4,5-BTC) counter-anion, a 4,5-diaza-fluoren-9-one (DAFO) mol-ecule and an uncoordinated water mol-ecule. In the crystal structure, O-H?O and O-H?N hydrogen bonds link the cations, anions and water mol-ecules into a three-dimensional network.

1000-01-01 | S-EPMC3006871 | BioStudies

Diaqua-bis(9-oxo-4,5-diaza-fluoren-3-olato-?N,O)cadmium(II).

Project description:The title compound, [Cd(C(11)H(5)N(2)O(2))(2)(H(2)O)(2)], is a mononuclear complex consisting of a Cd(II) atom, two 3-hydr-oxy-4,5-diaza-fluoren-9-one ligands and two coordinated water mol-ecules. The Cd(II) atom, lying on a twofold axis, displays a distorted octa-hedral coordintion. Adjacent mol-ecules are linked by O-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.84?(1)?Å], leading to a one-dimensional chain. Weak C-H?O hydrogen bonds connect the chains into a two-dimensional supra-molecular structure.

2008-01-01 | S-EPMC2960196 | BioStudies

(4,5-Diaza-fluoren-9-one-?N,N')bis-(1H-imidazole-?N)bis-(thio-cyanato-?N)cobalt(II).

Project description:In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octa-hedral coordination with the N atoms of the 4,5-diaza-fluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thio-cyanate ligand. Inter-molecular N-H?O hydrogen bonding forms a one-dimensional motif parallel to the cell ab diagonal.

1000-01-01 | S-EPMC3200902 | BioStudies

N-(4,5-Diaza-fluoren-9-yl-idene)aniline.

Project description:In the mol-ecule of the title compound, C(17)H(11)N(3), the 4,5-diaza-fluorenyl-idene unit is nearly planar and is oriented with respect to the phenyl ring at a dihedral angle of 75.75?(3)°. In the crystal structure, the mol-ecules are aligned in the [100] direction in such a way that neighbouring 4,5-diaza-fluorenyl-idene planes face each other in an anti-parallel fashion.

2008-01-01 | S-EPMC2961656 | BioStudies

9-[4,5-Bis(benzyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-4,5-diaza-fluorene.

Project description:In rhe title compound, C(28)H(20)N(2)S(4), the 1,3-dithiol-2-yl-idene and 4,5-diaza-fluoren-9-one (dafone) groups are almost coplanar, making a dihedral angle of only 5.65?(4)°. The two benzyl groups are on different sides of the 1,3-dithiol-2-yl-idene ring, forming a dihedral angle of 35.54?(2)°.

1000-01-01 | S-EPMC2961804 | BioStudies

(4,5-Diaza-fluoren-9-one-?N,N')bis-(thio-cyanato-?S)mercury(II).

Project description:In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H?N and C-H?O hydrogen bonds are effective in the stabilization of the structure.

1000-01-01 | S-EPMC3099883 | BioStudies

N-(4,5-Diaza-fluoren-9-yl-idene)-4-methyl-aniline.

Project description:In the mol-ecule of the title compound, C(18)H(13)N(3), the 4,5-diaza-fluorenyl-idene unit is nearly planar and is oriented at a dihedral angle of 66.31?(1)° with respect to the benzene ring. In the crystal structure, mol-ecules are stacked regularly along the c axis.

1000-01-01 | S-EPMC2967858 | BioStudies

4,5-Diaza-9H-fluoren-9-imine.

Project description:In the title compound, C(11)H(7)N(3), the diaza-fluorene rings are almost coplanar with an r.m.s. deviation of 0.0160?Å. In the crystal structure, C-H?N hydrogen bonds link mol-ecules into sheets parallel to the ab plane. Mol-ecules are also stacked regularly along the c axis by a variety of ?-? inter-actions with centroid-centroid distances in the range 3.527?(2)-3.908?(2)?Å.

1000-01-01 | S-EPMC3006907 | BioStudies

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data