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[?-Bis(trimethyl-silyl)amido]bis-[?-N,N-dimethyl-N',N''-bis-(trimethyl-silyl)guanidinato]-triangulo-tricopper(I).


ABSTRACT: The title compound, [Cu(3)(C(6)H(18)NSi(2))(C(9)H(24)N(3)Si(2))(2)], is a trinuclear Cu(I) complex. A crystallographic twofold axis passes through one Cu(I) atom and the N atom of the bis-(trimethyl-silyl)amide ligand that bridges between the other two Cu(I) atoms. The Cu-Cu bonds bridged by the guanadinate ligands [2.7913?(9)?Å] are slightly longer than the Cu-Cu bond bridged by the bis-(trimethyl-silyl)amide ligand [2.6405?(11)?Å].

SUBMITTER: Guo D 

PROVIDER: S-EPMC2968876 | BioStudies | 2009-01-01T00:00:00Z

REPOSITORIES: biostudies

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