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N-(2,6-Dichloro-phen-yl)-3-methyl-benzamide.

ABSTRACT: In the mol-ecular structure of the title compound, C(14)H(11)Cl(2)NO, the two aromatic rings form a dihedral angle of 70.9?(1)°. The central amido group -NH-C(=O)- makes a dihedral angle of 26.6?(2)° with the methyl-phenyl ring and 82.5?(1)° with the dichloro-phenyl ring. Inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the c axis of the crystal.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2971261 | BioStudies | 2009-01-01T00:00:00Z

REPOSITORIES: biostudies

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N-(2,6-Dichloro-phen-yl)benzamide.

Project description:The conformation of the N-H and C=O bonds in the structure of the title compound (N26DCPBA), C(13)H(9)Cl(2)NO, are anti to each other, similar to that observed in N-phenyl-benzamide (NPBA), N-(2-chloro-phen-yl)benzamide (N2CPBA), N-(2,3-dichloro-phen-yl)benzamide (N23DCPBA) and other benzanilides. The asymmetric unit of N26DCPBA contains two mol-ecules. The bond parameters in N26DCPBA are similar to those in NPBA, N2CPBA, N23DCPBA and other benzanilides. The amide group, -NHCO-, makes a dihedral angle of 30.8?(1)° with the benzoyl ring in the first mol-ecule and 35.1?(2)° in the second mol-ecule of the asymmetric unit. The dihedral angle between the two benzene rings (benzoyl and aniline) is 56.8?(1)° in the first mol-ecule and 59.1?(1)° in the second mol-ecule. N-H?O hydrogen bonds give rise to infinite chains running along the a axis of the crystal structure.

1000-01-01 | S-EPMC2960174 | BioStudies

N-(2,4-Dichloro-phen-yl)benzamide.

Project description:The conformations of the N-H and C=O bonds in the structure of the title compound, C(13)H(9)Cl(2)NO, are anti to each other, similar to that observed in N-phenyl-benzamide, N-(2-chloro-phen-yl)benzamide, N-(4-chloro-phen-yl)benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and other benzanilides. The amide -NHCO- group forms a dihedral angle of 33.0?(2)° with the benzoyl ring, while the rings are almost coplanar, making a dihedral angle of 2.6?(2)°). The mol-ecules are linked by N-H?O hydrogen bonds into infinite chains running along the b axis.

1000-01-01 | S-EPMC2961566 | BioStudies

2-Chloro-N-(2,6-dichloro-phen-yl)benzamide.

Project description:In the structure of the title compound (N26DCP2CBA), C(13)H(8)Cl(3)NO, the conformations of N-H and C=O bonds in the amide group are trans to each other, similar to that observed in N-(2,6-dichloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, 2-chloro-N-(2-chloro-phen-yl)benzamide and 2-chloro-N-(2,3-dichloro-phen-yl)benzamide with similar bond parameters. Furthermore, the position of the amide O atom is syn to the ortho-chloro group in the benzoyl ring. The amide group makes a dihedral angle of 59.8?(1)° with the benzoyl ring, while the benzoyl and aniline rings make a dihedral angle of 8.1?(2)°. The mol-ecules are linked by N-H?O hydrogen bonds into infinite chains running along the b axis.

2008-01-01 | S-EPMC2962123 | BioStudies

2-Chloro-N-(3,5-dichloro-phenyl)-benzamide.

Project description:The amide group in the structure of the title compound (N35DCP2CBA), C(13)H(8)Cl(3)NO, is trans-planar, similar to that observed in N-(3-chloro-phen-yl)benzamide, N-(3,5-dichloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide and other benzanilides. The C=O bond in N35DCP2CBA is anti to the ortho-chloro substituent in the benzoyl ring. The amide group makes dihedral angles of 63.1?(12) and 31.1?(17)°, respectively, with the benzoyl and aniline benzene rings, while the dihedral angle between the two benzene rings is 32.1?(2)°. The mol-ecules are linked into chains along the b axis by N-H?O hydrogen bonds.

2008-01-01 | S-EPMC2961721 | BioStudies

N-(4-Chloro-phen-yl)-3-methyl-benzamide.

Project description:In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N-H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central -NH-C(=O)- amido group makes a dihedral angle of 32.4?(1)° with the benzoyl ring and 36.1?(1)° with the anilino ring. The dihedral angle between the two benzene rings is 68.4?(1)°. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the a axis.

2009-01-01 | S-EPMC2971070 | BioStudies

2,4-Dichloro-N-cyclo-hexyl-benzamide.

Project description:In the title mol-ecule, C(13)H(15)Cl(2)NO, the cyclohexane ring adopts a chair conformation. The aromatic ring plane is oriented with respect to the N/O/C plane at a dihedral angle of 51.88?(7)°. In the crystal structure, inter-molecular N-H?O hydrogen bonds link the mol-ecules into infinite chains along the [010] direction.

2008-01-01 | S-EPMC2961337 | BioStudies

N-Isopropyl-benzamide.

Project description:In the title compound, C(10)H(13)NO, the dihedral angle between the amide group and the phenyl ring is 30.0?(3)°. In the crystal structure, inter-molecular N-H?O hydrogen bonds link mol-ecules into one-dimensional chains along the a axis.

1000-01-01 | S-EPMC2961603 | BioStudies

N-(Benzothia-zol-2-yl)-3-chloro-benzamide.

Project description:The title mol-ecule, C(14)H(9)ClN(2)OS, exists in the solid state in its amide form with a typical C=O bond length, as well as shortened C-N bonds. The plane containing the HNCO atoms subtends dihedral angles of 12.3?(4) and 8.1?(3)° with the planes of the phenyl ring and benzothia-zole group, respectively, whereas the dihedral angle between the planes of the phenyl ring and the benzothia-zole group is 5.96?(6)°. In the crystal, mol-ecules form inter-molecular N-H?N hydrogen bonds, generating independent scissor-like R(2) (2)(8) dimers.

1000-01-01 | S-EPMC2969761 | BioStudies

4,4'-Dichloro-N,N'-(o-phenyl-ene)dibenzene-sulfonamide.

Project description:The title compound, C(18)H(14)Cl(2)N(2)O(4)S(2), is a diamine that is a precursor to a quinonoid bidentate redox-active ligand. The dihedral angles between the central phenyl ring and the end rings are 87.5(1) and 60.7(1)°, while the two end rings make a dihedral angle of 82.5(1)°. The crystal structure is stabilized by two weak inter-molecular N-H?O hydrogen bonds, as well as one intra-molecular C-H?O and one N-H?N hydrogen bond.

1000-01-01 | S-EPMC2968088 | BioStudies

N-(Naphthalen-1-yl)benzamide.

Project description:In the title compound, C(17)H(13)NO, the N-H and C=O bonds are anti with respect to each other. The dihedral angle between the naphthalene ring system and the phenyl ring is 86.63?(5)°. In the crystal, N-H?O hydrogen bonds link mol-ecules into chains along [010].

1000-01-01 | S-EPMC3238870 | BioStudies

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