Dataset Information



ABSTRACT: The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethyl-amino-benzoate (DMAB), two diethyl-nicotinamide (DENA) ligands and two water mol-ecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni(II) atom is displaced by 0.681?(1)?Å out of the least-squares plane of the carboxyl-ate group. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 5.61?(7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20?(4)°. An intra-molecular O-H?O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, inter-molecular O-H?O and C-H?O hydrogen bonds link mol-ecules into a three-dimensional network. Two weak C-H?? inter-actions are also present.


PROVIDER: S-EPMC2977174 | BioStudies | 2009-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC2969431 | BioStudies
1000-01-01 | S-EPMC2977595 | BioStudies
2011-01-01 | S-EPMC3120545 | BioStudies
2011-01-01 | S-EPMC3089307 | BioStudies
1000-01-01 | S-EPMC3200662 | BioStudies
2012-01-01 | S-EPMC3414129 | BioStudies
1000-01-01 | S-EPMC2970090 | BioStudies
1000-01-01 | S-EPMC4910347 | BioStudies
1000-01-01 | S-EPMC3793697 | BioStudies
1000-01-01 | S-EPMC5137619 | BioStudies