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Di-?-benzoato-?O,O':O;?O:O,O'-bis-[(acetato-?O)(1,10-phenanthroline-?N,N')lead(II)] dihydrate.


ABSTRACT: The title compound, [Pb(2)(CH(3)COO)(2)(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water mol-ecules. Each Pb(II) unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb(II) atoms. The crystal packing is stabilized by O-H?O hydrogen bonds and by ?-? inter-actions between the phen rings of neighboring mol-ecules, with a centroid-centroid distance of 3.577?(3)?Å.

SUBMITTER: Gao J 

PROVIDER: S-EPMC2977393 | BioStudies | 2009-01-01T00:00:00Z

REPOSITORIES: biostudies

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