Unknown

Dataset Information

0

2-(4-Bromo-phen-yl)-1-(phenyl-sulfin-yl)naphtho[2,1-b]furan.


ABSTRACT: In the title compound, C(24)H(15)BrO(2)S, the sulfinyl O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane through the naphthofuran fragment. The phenyl ring is nearly perpendicular to the plane of the tricyclic naphthofuran system [81.77?(6)°] and is tilted slightly towards it. The 4-bromo-phenyl ring is rotated out of the naphthofuran plane by a dihedral angle of 31.12?(4)°. In the crystal structure, non-classical inter-molecular C-H?O and C-H?Br hydrogen bonds are observed. The crystal structure also exhibits aromatic ?-? inter-actions between the furan ring and the central benzene ring of the adjacent naphthofuran system [centroid-centroid distance = 3.768?(3)?Å]. In addition, inter-molecular C-Br?? inter-actions [3.866?(2)?Å] between the Br atom and the phenyl ring of the phenyl-sulfinyl substituent are present.

PROVIDER: S-EPMC2977400 | BioStudies |

REPOSITORIES: biostudies

Similar Datasets

| S-EPMC2977353 | BioStudies
| S-EPMC2969545 | BioStudies
| S-EPMC2977132 | BioStudies
2010-01-01 | S-EPMC2979164 | BioStudies
| S-EPMC2969341 | BioStudies
2009-01-01 | S-EPMC2969819 | BioStudies
| S-EPMC2970042 | BioStudies
| S-EPMC2977298 | BioStudies
| S-EPMC2970418 | BioStudies
| S-EPMC3007207 | BioStudies