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Oxonium (dihydrogen 1-amino-ethane-1,1-diyldiphospho-nato-?N,O)[hydrogen (1-amino-1-phosphono-ethyl)phospho-nato-?N,O]palladium(II) trihydrate.


ABSTRACT: The title compound, (H(3)O)[Pd(C(2)H(7)NO(6)P(2))(C(2)H(8)NO(6)P(2))]·3H(2)O, was synthesized by the reaction of [Pd(H(2)O)(4)](NO(3))(2) with 1-amino-ethane-1,1-diyldiphospho-nic acid in aqueous solution. The asymmetric unit contains one mol-ecule of the complex existing as an anion, an oxonium counter-ion and three solvent water mol-ecules. The Pd(II) ion occupies a position on a pseudo-twofold axis, which is not realized crystallographically. The slightly distorted square-planar coordination environment of the Pd(II) ion consists of the O atoms from two phospho-nic acid groups and two N atoms of the amino groups in cis positions. The crystal structure displays N-H?O and O-H?O hydrogen bonding, which creates a wide three-dimensional network.

SUBMITTER: Dudko A 

PROVIDER: S-EPMC2979892 | BioStudies | 2010-01-01T00:00:00Z

REPOSITORIES: biostudies

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