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4-Cyano-1-(4-nitro-benz-yl)pyridinium bis-(2-thioxo-1,3-dithiole-4,5-dithiol-ato-?S,S)nickelate(III).


ABSTRACT: In the title salt, (C(13)H(10)N(3)O(2))[Ni(C(3)S(5))(2)], the Ni(III) cation is S,S'-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiol-ate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097?(1)?Å. In the 1-(4-nitro-benz-yl)-4-cyano-pyridinium cation, the pyridine ring is twisted at a dihedral angle of 73.84?(16)° with respect to the benzene ring. ?-? stacking is observed between nearly parallel [dihedral angle = 4.71?(7)°] dithiole and benzene rings, the centroid-centroid distance being 3.791?(2)?Å.

SUBMITTER: Li KH 

PROVIDER: S-EPMC2983398 | BioStudies | 2010-01-01T00:00:00Z

REPOSITORIES: biostudies

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