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Bis(N-sec-butyl-N-n-propyl-dithio-carbamato-?S,S')(1,10-phenanthroline-?N,N')zinc(II).


ABSTRACT: Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H?S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551?(6)-0.725?(5).

SUBMITTER: Alzaalouk AS 

PROVIDER: S-EPMC3008025 | BioStudies | 2010-01-01T00:00:00Z

REPOSITORIES: biostudies

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