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Azido-[1,2-bis-(diphenyl-phosphan-yl)ethane-?P,P'](?-inden-yl)ruthenium(II).


ABSTRACT: Facile ligand substitution is observed when the ruthenium chloride complex [Ru(?(5)-C(9)H(7))Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN(3) in refluxing ethanol, yielding the title compound, [Ru(?(5)-C(9)H(7))(N(3))(dppe)] or [Ru(C(9)H(7))(N(3))(C(26)H(24)P(2))]. The Ru(II) atom has a typical piano-stool coordination. The Ru-P bond lengths are 2.284?(2) and 2.235?(2)?Å. NMR and MS analyses are in agreement with the structure of the title compound.

PROVIDER: S-EPMC3050413 | BioStudies |

REPOSITORIES: biostudies

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