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Hexaaqua-magnesium bis-{4-[(5-bromo-2-hy-droxy-benzyl-idene)amino]-benzene-sulfonate} dihydrate.

ABSTRACT: In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5?(2)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H?O and O-H?Br hydrogen bonds.

SUBMITTER: Tai XS

PROVIDER: S-EPMC3051451 | BioStudies | 2011-01-01

REPOSITORIES: biostudies

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Hexaaqua-cadmium(II) 2,2'-(azino-dimethyl-idyne)dibenzene-sulfonate dihydrate.

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Project description:In the title compound, [Cd(H(2)O)(6)](C(13)H(10)NO(4)S)(2)·2H(2)O, the Cd atom (site symmetry ) adopts a regular octa-hedral coordination and the anion is stabilized by an intra-molecular O-H?N hydrogen bond. O-H?O hydrogen bonds involving the coordinated and uncoordinated water mol-ecules lead to a three-dimensional network.

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