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Chloridobis(1,10-phenanthroline-?N,N')copper(I) dichloridocopper(II).


ABSTRACT: The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol-ecules and one chloride anion in a distorted trigonal-bipyramidal geometry. The Cu(II) complex cations form layers through ?-? stacking [interplanar distance = 3.481?(2)?Å]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure.

SUBMITTER: Meng Q 

PROVIDER: S-EPMC3051778 | BioStudies | 2011-01-01T00:00:00Z

REPOSITORIES: biostudies

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