Unknown

Dataset Information

0

Catena-Poly[[octa-aqua-bis-(?(4)-benzene-1,3,5-tricarboxyl-ato)trizinc] tetra-hydrate].


ABSTRACT: In the title compound, {[Zn(3)(C(9)H(3)O(6))(2)(H(2)O)(8)]·4H(2)O}(n), there are two crystallographically independent Zn(II) ions. One presents a trigonal-bipyramidal coordination geometry defined by five O atoms [three from two carboxyl-ate groups of two benzene-1,3,5-tricarboxyl-ate (BTC) ligands and the other two deriving from three water mol-ecules], while the other lies on an inversion centre and exists in a slightly distorted octa-hedral coordination geometry defined by six O atoms (two from two carboxyl-ate groups of two BTC ligands and the others from four water mol-ecules). A three-dimensional framework is further strengthened via O-H?O hydrogen-bonding inter-actons.

SUBMITTER: Sun L 

PROVIDER: S-EPMC3089220 | BioStudies | 2011-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC3152031 | BioStudies
1000-01-01 | S-EPMC3212115 | BioStudies
1000-01-01 | S-EPMC3120569 | BioStudies
2012-01-01 | S-EPMC3379189 | BioStudies
1000-01-01 | S-EPMC3247557 | BioStudies
1000-01-01 | S-EPMC3274850 | BioStudies
2011-01-01 | S-EPMC3238732 | BioStudies
1000-01-01 | S-EPMC3050173 | BioStudies
1000-01-01 | S-EPMC3919546 | BioStudies
2015-01-01 | S-EPMC4518996 | BioStudies