Unknown

Dataset Information

0

{1,2-Bis[(3,5-dimethyl-1H-pyrazol-1-yl-?N)meth-yl]benzene}-dichloridozinc(II).


ABSTRACT: The title zinc complex, [ZnCl(2)(C(18)H(22)N(4))], contains a bidentate 1,2-bis(3,5-dimethyl-1H-pyrazol-1-ylmeth-yl)benz-ene ligand that binds to the zinc atom, forming a nine-membered metallocyclic ring. The geometry about the Zn atom is distorted tetra-hedral, with the largest deviation observed in the magnitude of the Cl-Zn-Cl angle. Similar distortions are observed in the cobalt analogue and related zinc compounds containing metallocyclic rings with more than six members. The copper analogue exhibits a more severe distortion of the metal coordination sphere than is observed in the title compound.

SUBMITTER: Guzei IA 

PROVIDER: S-EPMC3238634 | BioStudies | 2011-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC2977457 | BioStudies
1000-01-01 | S-EPMC3052059 | BioStudies
1000-01-01 | S-EPMC2961892 | BioStudies
1000-01-01 | S-EPMC2914944 | BioStudies
1000-01-01 | S-EPMC2969561 | BioStudies
2011-01-01 | S-EPMC3201249 | BioStudies
2009-01-01 | S-EPMC2972039 | BioStudies
1000-01-01 | S-EPMC3253618 | BioStudies
2010-01-01 | S-EPMC3011725 | BioStudies
2013-01-01 | S-EPMC3569184 | BioStudies