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Catena-Poly[[(1,10-phenanthroline-?N,N')zinc]-?-4-sulfonato-benzo-triazolido-?N,O:N].


ABSTRACT: In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato-benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol-ecule and a sulfonate O atom from a 4-sulfonato-benzotriazolide anion, displaying a distorted ZnN(4)O trigonal-bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonato-benzotriazolide ions act as ?(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C-H?O hydrogen-bonding inter-actions.

SUBMITTER: Cheng XC 

PROVIDER: S-EPMC3238664 | BioStudies | 2011-01-01

REPOSITORIES: biostudies

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