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[?-Bis(diphenyl-phosphan-yl-?P)methane]-deca-carbonyl-tri-?-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate.


ABSTRACT: In the title compound, [Re(3)(?-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis-(diphenyl-phosphan-yl)methane ligand bridges two Re atoms. Neglecting the Re-Re inter-actions, each Re atom is in a slightly distorted octa-hedral coordination environment. The dichloro-methane solvent mol-ecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.

SUBMITTER: Abdel-Magied AF 

PROVIDER: S-EPMC3238719 | BioStudies | 2011-01-01T00:00:00Z

REPOSITORIES: biostudies

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