Unknown

Dataset Information

0

Poly[(?(2)-4,4'-bipyridine-?N:N')(?(2)-2,2-dimeth-yl-cyclo-pentane-1,3-dicarboxyl-ato-?O,O:O,O)cadmium].


ABSTRACT: In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4'-bipyridine ligands and two 2,2-dimethyl-cyclo-pentane-1,3-dicarboxyl-ate ions. The carboxyl-ate ion and the N-heterocycle both function as bridges to link adjacent Cd(II) atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C-C bond of the 4,4'-bipyridine ligand is located on an inversion center. In the crystal, the carboxyl-ate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring.

SUBMITTER: Zhang XF 

PROVIDER: S-EPMC3247004 | BioStudies | 2011-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC3051519 | BioStudies
1000-01-01 | S-EPMC2971117 | BioStudies
2011-01-01 | S-EPMC3201505 | BioStudies
1000-01-01 | S-EPMC3247000 | BioStudies
2012-01-01 | S-EPMC3297229 | BioStudies
1000-01-01 | S-EPMC2959802 | BioStudies
1000-01-01 | S-EPMC2971152 | BioStudies
2009-01-01 | S-EPMC2970416 | BioStudies
1000-01-01 | S-EPMC3200682 | BioStudies
2009-01-01 | S-EPMC2969229 | BioStudies