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Catena-Poly[[[triaqua-cobalt(II)]-?-10-methyl-phenothia-zine-3,7-dicarboxyl-ato] monohydrate].


ABSTRACT: The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methyl-phenothia-zine-3,7-dicarboxyl-ate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxyl-ate groups and three water mol-ecules, displays a distorted octa-hedral environment. In the crystal, ?-? inter-chain inter-actions, with centroid-centroid distances of 3.656?(2) and 3.669?(2)?Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O-H?O hydrogen-bonding inter-actions between the coordinating water mol-ecules and carboxyl-ate O atoms link the sheets into a three-dimensional network.

PROVIDER: S-EPMC3343812 | BioStudies | 2012-01-01T00:00:00Z

REPOSITORIES: biostudies

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