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(Acetyl-acetonato-?(2)O,O')[(2-bromo-phen-yl)diphenyl-phosphane-?P]carbonyl-rhodium(I).


ABSTRACT: In the title compound, [Rh(C(5)H(7)O(2))(C(18)H(14)BrP)(CO)], the Rh(I) atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh-O = 2.077?(2) and 2.033?(2)?Å] of the acetyl-acetonate ligand, one carbonyl C atom [Rh-C = 1.813?(2)?Å] and one P atom [Rh-P = 2.242?(5)?Å] of the PPh(2)(2-BrC(6)H(4)) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data.

SUBMITTER: Davis WL 

PROVIDER: S-EPMC3343868 | BioStudies | 2012-01-01T00:00:00Z

REPOSITORIES: biostudies

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