Unknown

Dataset Information

0

Catena-Poly[copper(I)-di-?-bromido-copper(I)-bis-[?-4-methyl-1H-1,2,4-triazole-5(4H)-thione-?(2)S:S]].


ABSTRACT: In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H?N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-H?Br inter-actions also occur.

SUBMITTER: Saithong S 

PROVIDER: S-EPMC3344317 | BioStudies | 2012-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC2977598 | BioStudies
2008-01-01 | S-EPMC2959303 | BioStudies
2012-01-01 | S-EPMC3470141 | BioStudies
1000-01-01 | S-EPMC2977283 | BioStudies
1000-01-01 | S-EPMC3297220 | BioStudies
1000-01-01 | S-EPMC3588773 | BioStudies
1000-01-01 | S-EPMC4051018 | BioStudies
1000-01-01 | S-EPMC2961882 | BioStudies
1000-01-01 | S-EPMC3007837 | BioStudies
2010-01-01 | S-EPMC3007341 | BioStudies