Catena-Poly[copper(I)-di-?-bromido-copper(I)-bis-[?-4-methyl-1H-1,2,4-triazole-5(4H)-thione-?(2)S:S]].
Ontology highlight
ABSTRACT: In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H?N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-H?Br inter-actions also occur.
SUBMITTER: Saithong S
PROVIDER: S-EPMC3344317 | BioStudies | 2012-01-01T00:00:00Z
REPOSITORIES: biostudies
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