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Poly[[[?-3,3'-(dimethyl-silanedi-yl)dibenzoato][?-1,1'-(1,4-phenyl-ene)di-1H-imidazole]-zinc] monohydrate].

ABSTRACT: The asymmetric unit of the title compound, {[Zn(C??H??O?Si)(C??H??N?)]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3'-(dimethyl-silanedi-yl)dibenzoate ligands and two half 1,1'-(1,4-phenyl-ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxyl-ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol-ecules are hydrogen bonded within the chain along the c axis.

PROVIDER: S-EPMC3393147 | BioStudies | 2012-01-01T00:00:00Z

REPOSITORIES: biostudies

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