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[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-?N]hydrazin-1-yl-idene-?N¹}eth-yl)phenolato-?O](pyridine-?N)nickel(II).


ABSTRACT: The Ni(II) atom in the title complex, [Ni(C??H??N?OS)(C?H?N)], exists within a square-planar N?O donor set provided by N,N',O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N-Ni-N five-membered chelate bite angle of 83.28?(12)°. The pyridine mol-ecule forms a dihedral angle of 44.43?(6)° with the N?O donor set. Supra-molecular stacks along the a axis mediated by alternating ?-? inter-actions between the pyridine and five- [centroid-centroid distance = 3.4784?(16)?Å] and six-membered [3.4633?(17)?Å] chelate rings, feature in the crystal packing.

PROVIDER: S-EPMC3393181 | BioStudies |

REPOSITORIES: biostudies

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