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Enantioselective thiourea-catalyzed intramolecular cope-type hydroamination.


ABSTRACT: Catalysis of Cope-type rearrangements of bis-homoallylic hydroxylamines is demonstrated using chiral thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched ?-substituted pyrrolidine products and represents a complementary approach to metal-catalyzed methods.

SUBMITTER: Brown AR 

PROVIDER: S-EPMC3689223 | BioStudies | 2013-01-01

REPOSITORIES: biostudies

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