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Anodic coupling of carboxylic acids to electron-rich double bonds: A surprising non-Kolbe pathway to lactones.


ABSTRACT: Carboxylic acids have been electro-oxidatively coupled to electron-rich olefins to form lactones. Kolbe decarboxylation does not appear to be a significant competing pathway. Experimental results indicate that oxidation occurs at the olefin and that the reaction proceeds through a radical cation intermediate.

SUBMITTER: Perkins RJ 

PROVIDER: S-EPMC3778411 | BioStudies | 2013-01-01T00:00:00Z

REPOSITORIES: biostudies

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