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Synthesis and applications of ?-trifluoromethylated alkylboron compounds.


ABSTRACT: RBF3 K is a chemist's BFF: A metal-free synthetic route to unprecedented organoboron compounds bearing an ?-trifluoromethyl substituent, employing a variety of trifluoroborate (RBF3 K) starting materials, is reported. These substrates represent the first isolated ?-trifluoromethylated alkylboron building blocks, and these reagents lead to a variety of useful bench-stable, synthetic intermediates. Pin=pinacol.

SUBMITTER: Argintaru OA 

PROVIDER: S-EPMC3904770 | BioStudies | 2013-01-01

REPOSITORIES: biostudies

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