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Bis(1,10-phenanthrolin-1-ium) tetra-chlorido-zincate monohydrate.


ABSTRACT: In the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol-ecule and the tetrahedral tetrachloridozincate anion via N-H?O, O-H?Cl and N-H?Cl hydrogen bonds, forming chains along [100]. The chains are linked via C-H?Cl hydrogen bonds and a number of ?-? inter-actions [centroid-centroid distances vary from 3.5594?(14) to 3.7057?(13)?Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N-H?N inter-action.

SUBMITTER: Govindan E 

PROVIDER: S-EPMC3998259 | BioStudies | 2014-01-01

REPOSITORIES: biostudies

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