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Crystal structure of bis-(acetato-?O)bis-(pyridine-2-carboxamide oxime-?(2) N,N')cadmium ethanol disolvate.


ABSTRACT: In the title compound, [Cd(CH3COO)2(C6H7N3O)2]·2C2H5OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N'-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex mol-ecules are assembled into chains along the c-axis direction via N-H?O hydrogen-bonding inter-actions. These chains are further assembled by O-H?O hydrogen bonds involving the ethanol solvent mol-ecules into a three-dimensional supramolecular structure.

SUBMITTER: Liu J 

PROVIDER: S-EPMC4186130 | BioStudies | 2014-01-01T00:00:00Z

REPOSITORIES: biostudies

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