Unknown

Dataset Information

0

Crystal structure of 4,5-bis-(3,4,5-tri-meth-oxy-phen-yl)-2H-1,2,3-triazole methanol monosolvate.


ABSTRACT: The title compound, C20H23N3O6·CH3OH, was synthesized by [3 + 2] cyclo-addition of (Z)-2,3-bis-(3,4,5-tri-meth-oxy-phen-yl)acrylo-nitrile with sodium azide and ammonium chloride in DMF/water. The central nitro-gen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-tri-meth-oxy-phenyl ring planes are 34.31?(4) and 45.03?(5)°, while that between the 3,4,5-tri-meth-oxy-phenyl rings is 51.87?(5)°. In the crystal, the mol-ecules, along with two methanol solvent mol-ecules are linked into an R (4) 4(10) centrosymmetric dimer by N-H?O and O-H?N hydrogen bonds.

SUBMITTER: Madadi NR 

PROVIDER: S-EPMC4257191 | BioStudies | 2014-01-01

REPOSITORIES: biostudies

Similar Datasets

2014-01-01 | S-EPMC4257209 | BioStudies
2016-01-01 | S-EPMC4908540 | BioStudies
2020-01-01 | S-EPMC7405576 | BioStudies
1000-01-01 | S-EPMC4908538 | BioStudies
1000-01-01 | S-EPMC3998339 | BioStudies
1000-01-01 | S-EPMC2983739 | BioStudies
1000-01-01 | S-EPMC4647442 | BioStudies
1000-01-01 | S-EPMC5382604 | BioStudies
2010-01-01 | S-EPMC3011481 | BioStudies
1000-01-01 | S-EPMC3007452 | BioStudies