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Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt(2+) Catalysts.


ABSTRACT: The combination of the N-based pincer ligand PyBOX with Pt(2+) leads to new catalysts for the enantioselective cycloisomerization of dienyl- and trienyl-ols. The mechanistic combination of electrophilic cyclization followed by rapid protodemetalation is surprising and leads to a powerful construct for developing new reactions.

SUBMITTER: Nguyen H 

PROVIDER: S-EPMC4372115 | BioStudies | 2014-01-01

REPOSITORIES: biostudies

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