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Crystal structure of bis-(quinolin-1-ium) tetra-chlorido-ferrate(III) chloride.


ABSTRACT: The asymmetric unit of the title hybrid compound, (C9H8N)[FeCl4]Cl, comprises a tetra-hedral tetra-chlorido-ferrate(III) anion, [FeCl4](-), a Cl(-) anion and two quinolinium cations. There are N-H?Cl hydrogen-bonding inter-actions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with ?-? stacking between adjacent quinolinium rings [centroid-to-centroid distances between C6 and C5N rings in adjacent stacked quinolinium cations of 3.609?(2) and 3.802?(2)?Å] serve to hold the structure together.

SUBMITTER: Boudjarda A 

PROVIDER: S-EPMC4719870 | BioStudies | 2015-01-01T00:00:00Z

REPOSITORIES: biostudies

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