Unknown

Dataset Information

0

Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides.


ABSTRACT: An efficient palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides has been developed. The reaction proceeds under mild reaction conditions with high efficiency and excellent functional group tolerance, even towards formyl and hydroxy groups. Preliminary mechanistic studies reveal that a secondary trifluoromethylated alkyl radical is involved in the reaction.

SUBMITTER: Fan T 

PROVIDER: S-EPMC5727777 | BioStudies | 2017-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

2018-01-01 | S-EPMC6328373 | BioStudies
2012-01-01 | S-EPMC3432975 | BioStudies
2018-01-01 | S-EPMC6137405 | BioStudies
2017-01-01 | S-EPMC5728111 | BioStudies
2019-01-01 | S-EPMC7557108 | BioStudies
1000-01-01 | S-EPMC6115631 | BioStudies
2018-01-01 | S-EPMC5813498 | BioStudies
2012-01-01 | S-EPMC3432578 | BioStudies
2016-01-01 | S-EPMC5335917 | BioStudies
2019-01-01 | S-EPMC6349022 | BioStudies