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Supercooling of functional alkyl-? molecular liquids.

ABSTRACT: Metastable states of soft matters are extensively used in designing stimuli-responsive materials. However, the non-steady properties may obstruct consistent performance. Here we report an approach to eradicate the indistinguishable metastable supercooled state of functional molecular liquids (FMLs), which remains as a liquid for weeks or months before crystallizing, via rational molecular design. The phases (solid, kinetically stable liquid, and supercooled liquid) of a model FML, branched alkyl chain-substituted 9,10-diphenylanthracene (DPA), are found to be governed by subtle alterations of the molecular structure (alkyl-DPA ratio and bulkiness of the DPA unit). We thus outline molecular design principles to avoid supercooled FML formation. Moreover, we demonstrate a practical technique to rapidly discriminate supercooled FMLs (within 5 h) by accelerating their crystallization in differential scanning calorimetry heating via pre-annealing or relatively slow scanning.


PROVIDER: S-EPMC6166271 | BioStudies | 2018-01-01

REPOSITORIES: biostudies

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