Dataset Information


Bimetallic nickel-cobalt hydrides in H2 activation and catalytic proton reduction.

ABSTRACT: The synergism of the electronic properties of nickel and cobalt enables bimetallic NiCo complexes to process H2. The nickel-cobalt hydride [(dppe)Ni(pdt)(H)CoCp*]+ ([1H]+ ) arising from protonation of the reduced state 1 was found to be an efficient electrocatalyst for H2 evolution with Cl2CHCOOH, and the oxidized [Ni(ii)Co(iii)]2+ form is capable of activating H2 to produce [1H]+ . The features of stereodynamics, acid-base properties, redox chemistry and reactivity of these bimetallic NiCo complexes in processing H2 are potentially related to the active site of [NiFe]-H2ases.

PROVIDER: S-EPMC6340403 | BioStudies | 2019-01-01T00:00:00Z

REPOSITORIES: biostudies

Similar Datasets

| S-EPMC6468968 | BioStudies
| S-EPMC5029088 | BioStudies
| S-EPMC6469242 | BioStudies
| S-EPMC6644433 | BioStudies
| S-EPMC5071703 | BioStudies
| S-EPMC4364603 | BioStudies
| S-EPMC6771717 | BioStudies
| S-EPMC7770839 | BioStudies
| S-EPMC4895212 | BioStudies
| S-EPMC7804276 | BioStudies