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Acid Catalyzed Formation of C⁻C and C⁻S Bonds via Excited State Proton Transfer.


ABSTRACT: The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed condensation of 1,2,3,4-tetrahydroisoquinoline with aldehydes.

SUBMITTER: Strada A 

PROVIDER: S-EPMC6480163 | BioStudies | 2019-01-01

REPOSITORIES: biostudies

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