Dataset Information


Transition Metal (Fe, Co, Ni) Nanoparticles on Selective Amino-N-Doped Carbon as High-Performance Oxygen Reduction Reaction Electrocatalyst.

ABSTRACT: Metal-air batteries are attracting increasing attention as a superior renewable energy conversion device due to their high performance and strong potential. However, the high cost and low stability of the current Pt catalyst is the main obstacle preventing wide industrial application. In this work, we applied a plasma process to fabricate aniline and a transition metals electrode (Fe, Co, Ni) as the carbon-nitrogen and the metal nanoparticle (NP) precursors, respectively, for selective metal/amino-N-doped carbon catalysts. All three as-synthesized catalysts exhibited dominant amino-N as the major C-N bonding state. In electrochemical testing, Co/amino-N-doped carbon showed positive E1/2 potential (0.83 V vs. Reversible Hydrogen Electrode (RHE)). In addition, the calculated electron transfer number (n) of Co/amino-N-doped carbon at 0.5 V vs. RHE was 3.81, which was only slightly less than that of commercial Pt/C (3.97). This superior performance of transition metal/amino-N-doped carbon promotes it as an economical oxygen reduction reaction (ORR) electrocatalyst to replace expensive Pt/C in metal-air batteries.


PROVIDER: S-EPMC6566341 | BioStudies | 2019-01-01

REPOSITORIES: biostudies

Similar Datasets

1000-01-01 | S-EPMC6051395 | BioStudies
| S-EPMC6348107 | BioStudies
2020-01-01 | S-EPMC7040484 | BioStudies
1000-01-01 | S-EPMC4933978 | BioStudies
2020-01-01 | S-EPMC7674447 | BioStudies
2019-01-01 | S-EPMC6722099 | BioStudies
1000-01-01 | S-EPMC6018999 | BioStudies
1000-01-01 | S-EPMC6013824 | BioStudies
2019-01-01 | S-EPMC6647991 | BioStudies
2020-01-01 | S-EPMC7663306 | BioStudies