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Crystal structure of bis-[di-hydro-bis-(pyrazol-1-yl)borato-κ2 N 2,N 2'](1,10-phenanthroline-κ2 N,N')zinc(II).


ABSTRACT: The asymmetric unit of the title compound, [Zn(C6H8N4B)2(C12H8N2)], comprises one half of a ZnII cation (site symmetry 2), one di-hydro-bis-(pyrazol-1-yl)borate ligand in a general position, and one half of a phenanthroline ligand, the other half being completed by twofold rotation symmetry. The ZnII cation is coordinated in form of a slightly distorted octa-hedron by the N atoms of a phenanthroline ligand and by two pairs of N atoms of symmetry-related di-hydro-bis-(pyrazol-1-yl)borate ligands. The discrete complexes are arranged into columns that elongate in the c-axis direction with a parallel alignment of the phenanthroline ligands, indicating weak π-π inter-actions.

SUBMITTER: Ossinger S 

PROVIDER: S-EPMC6690474 | BioStudies | 2019-01-01

REPOSITORIES: biostudies

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