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Stereoselective Allylic Alkylations of Amino Ketones and Their Application in the Synthesis of Highly Functionalized Piperidines.


ABSTRACT: Chelated ketone enolates are excellent nucleophiles for allylic alkylations. Electron-withdrawing groups on the allyl moiety allow subsequent intramolecular Michael additions giving rise to piperidines with up to five stereogenic centers.

SUBMITTER: Prudel C 

PROVIDER: S-EPMC7079034 | BioStudies | 2020-01-01

REPOSITORIES: biostudies

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